mdc200v3_resin_sds_us_-_june_9_2015 SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-SIDE RESIN
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Section 1: Chemical, Product and Company Information
Product Name: ICYNENE PROSEALTM B-Side Resin also known as MD-C-200TM V3
ICYNENE MD-C-200TM and ICYNENE PROSEALTM are trademarks of
Icynene Inc.
Product Code: ICYNENE PROSEALTM B-SIDE RESIN
Product Use: Blend of polymeric resins and additives that react with polymeric methylene diisocyanate to create PROSEALTM foam, a semi-rigid
closed cell polyurethane foam for building and other construction insulation and protection. For professional and industrial use only.
Company Information: Icynene Inc., 6747 Campobello Rd., Mississauga, Ontario, L5N 2L7, Canada
Tel: 905.363.4040 Toll Free: 800.758.7325 Fax: 905.363.0102
Section2: Hazards Identification
Classification Acute Toxicity: oral, Category 4
Acute Toxicity: Skin, Category 5 Skin Corrosion/Irritation, Category 1A
Serious Eye Damage/Eye Irritation, Category 2B Specific Target Organ Toxicity (repeated exposure) [central nervous system (CNS) and kidneys] – Category
2 Specific Target Organ Toxicity (single exposure) [central nervous system (CNS) and kidneys] – Category2
Component CAS No. Wt %
1,1,1,3,3-Pentafluorobutane 406-58-6 13 – 30
Tris(1-chloro-2-propyl) phosphate 13674-84-5 7 – 13 1,1,1,2,3,3,3-Heptafluoropropane 431-89-0 1 – 5 Bis(3-dimethylaminopropyl)-n,n-
dimethylpropandiamine
33329-35-0 1 - 10
N-cyclohexyl-methylcyclohexanamine 7560-83-0 1-7
Pentamethyldiethylenetriamine 3030-47-5 1-7
Section 3: Composition/Information on Ingredients
MATERIAL SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-Side Resin
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Section 4: First Aid Measures
Eye: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 20 minutes. Get medical attention.
Skin: Clean exposed skin with soap and plenty of water. Remove
contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Inhalation: Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. Get medical attention. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Ingestion: Get medical attention immediately. Wash out mouth with water. Move
exposed person to fresh air. Can enter lungs and cause damage. Do not induce vomiting. Chemical burns must be treated promptly by a
physician. Never give anything by mouth to an unconscious person.
Notes to physician: Adrenalin and similar sympathomimetic drugs should be avoided
following exposure as cardiac arrhythmia may result with possible subsequent cardiac arrest. Symptomatic treatment and supportive
therapy as indicated. Following severe exposure the patient should be kept under medical review for at least 48 hours as delayed pulmonary
edema may develop.
Section 5: Fire Fighting Measures
Flash Point: Not Available
Method Used: Not Available
Flammable Limits:
LFL:
UFL:
Not Available
Not Available
Extinguishing Media: Carbon dioxide, dry chemical, foam. In case of large fires, water spray
should be used. Use an extinguishing agent suitable for the surrounding fire.
Explosion Hazards: In a fire or if heated, a pressure increase will occur and the container may burst. In use, may form flammable/explosive vapor-air mixture if no
proper ventilation is in place.
Fire Hazards: Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
MATERIAL SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-Side Resin
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Hazardous Combustion
Products
Carbon dioxide, carbon monoxide, nitrogen oxides, Dense black smoke,
Other potentially toxic fumes.
Fire Fighting Equipment: Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6: Accidental Release Measures
Personal Precautions: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment
Environmental
Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.
Methods for Cleaning Up: Stop leak if without risk. Move containers from spill area. Approach
release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste
disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Section 7: Handling and Storage
Handling Put on appropriate personal protective equipment (see section 8).
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands
and face before eating, drinking and smoking. Persons with a history of skin sensitization problems should not be employed in any process
in which this product is used. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do
not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container
or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Storage Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials (see section 10) and food and drink. Recommended storage temperature (Min/Max): 23 - 30°C. If materials
are received outside the recommended temperature, condition the materials for 24 hours before use. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in
MATERIAL SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-Side Resin
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unlabeled containers. Use appropriate containment to avoid
environmental contamination. Make sure there is adequate ventilation to prevent localized vapor accumulation.
Section 8: Exposure Controls/Personal Protection
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations below
the TLV. Suitable respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. The
local exhaust ventilation must be independent of HVAC system, such as furnace, air conditioning, etc. The ventilation equipment should be
running during and after the installation process. HVAC system should be turned off during and 24 hours after the installation.
Respiratory Protection: Sprayers and Helpers must always wear Supplied-Air Respirators with full-face protection (hood or full-face piece type) when spraying. When
handling the foam product, it is essential that at a minimum workers were properly fit-tested NIOSH approved Air Purifying Respirator.
Skin Protection: Sprayers and helpers must always wear chemically resistant gloves and full body protection to prevent skin contact. There should be no skin
exposed during handling, processing or application of Icynene™ spray foam products.
Eye Protection: Goggles or shield safety eyewear complying with an approved standard should be used when handling or spraying the foam products to avoid
eye exposure to liquid splashes, mists or dusts. Hands Butyl Rubber, Nitrile Rubber and Neoprene Chemical-resistant, impervious gloves complying with an approved standard should be worn
at all times when handling the foam chemical products.
Section 9: Physical and Chemical Properties
Physical State: Brown liquid
Boiling Point: Not Available
Vapour Pressure: Not Available
Freezing Point: Not Available
Vapour Density: Not Available
Solubility in Water: Not Available
VOC content Not Available
Specific Gravity: 1.2
Odour: Amine Odour
pH: 10.5-11.5
Viscosity: 250-450 cps at 25°C Brookfield Spindle #1 at 20 RPM
Coefficient of Water/Oil
Distribution
Not Available
Section 10: Stability and Reactivity
MATERIAL SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-Side Resin
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Stability: This product is stable under normal conditions.
In use, it may form localized flammable/explosive vapour-air mixture if ventilation is inadequate.
Incompatibility: Reactive or incompatible with the following materials: oxidizing materials, organic materials, metals, acids and alkalis, and
isocyanates.
Shelf-Life: Six months
Hazardous Polymerization: Under normal conditions of storage and use, hazardous polymerization will not occur.
Section 11: Toxicological Information
Potential Acute Health Effects: Ingestion Harmful if swallowed
Inhalation Irritating to respiratory system. Eyes Severely irritating to eyes. Risk of serious damage to eyes
Skin Harmful and severely irritating to skin. May cause skin sensitization. Potential Chronic Health Effects:
Chronic Effects: Contains material that may cause target organ damage, based on animal data.
Target Organs: Cardiovascular system, central nervous system Carcinogenicity: No known significant effects or critical hazards
Mutagenicity: No known significant effects or critical hazards Teratogenicity: Contains material which can cause birth defects.
Fertility Effect: No known significant effects or critical hazards Developmental Effects: No known significant effects or critical hazards
Section 12: Ecological Information/Environmental Fate
Aquatic Ecotoxicity: Not Available
Biodegradability: Not Available
Environmental Effects: The majority of this product is intended to react with co-reactant polymeric diisocyanate MDI and form solid foam prodcuct staying in place of service.
Little environmentally harmful chemicals will be released to the environment. This product may be harmful to the environment if accidentally released in
large quantities.
Section 13: Spill, Leak and Disposal Procedures
Major Spill: Call Icynene Inc. (800) 758-7325. If transportation spill involved call CANUTEC (613) 996-6666
Minor Spill: Absorb the resin with sawdust or other absorbent. Scoop up solid absorbent for waste disposal. The area should then be washed down
to dilute and remove the remaining traces of material.
Disposal Method: The generation of waste should be avoided or minimized wherever
possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of
MATERIAL SAFETY DATA SHEET
Product Name: ICYNENE PROSEALTM B-Side Resin
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environmental protection and waste disposal legislation and any
regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14: Transport Information
TDG (TRANSPORTATION OF DANGEROUS GOODS) CLASSIFICATION: Not Regulated.
Section 15: Regulatory Information
CANADA:
CEPA (DSL) All components are listed or exempted.
WHMIS: D2A: Material causing other toxic effects (Very Toxic)
D2B: Material causing other toxic effects (Toxic).
This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
Section 16: Other Information
References:
- Canadian Guide of the Law and Regulations of the Transportation of Dangerous Goods - Controlled Products Regulations
- Manufacturer’s Material Safety Data Sheets
Manufacturer Disclaimer:
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED
AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY
OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED ICYNENE EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE, DATA SHEETS FOR ICYNENE PRODUCTS.
DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR
TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM ICYNENE. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA
SHEET SHOULD BE DIRECTED TO ICYNENE, MANUFACTURING MANAGER, PRODUCT SAFETY, AT THE ABOVE-NOTED ADDRESS.
PREPARATION INFORMATION:
Revision Version and Date: June 9, 2015
Prepared by: Icynene Inc.
Telephone: 1.800.758.7325
Icynene spray foam insulation products have an excellent health and
safety record spanning more than 350,000 projects over more than 25
years. Nonetheless, safe handling practices during and immediately
following installation are required to eliminate the possibility of health
effects from exposure to isocyanates. Asthma, other lung problems, and
irritation of the nose and throat can result from inhalation of isocyanates.
Direct contact with the skin and eyes can result in irritation. Different
individuals will react differently to the same exposures; some will be
more sensitive than others. Severe asthma attacks have been reported
in some sensitized workers exposed repeatedly to isocyanates while not
wearing proper protective equipment. Some reports indicate a reaction
and sensitization can occur following a single, sustained occupational
exposure to isocyanates without proper protective equipment above
the OSHA permissible exposure limit. But sensitization might not occur
immediately in some individuals. Consistent use of personal proper
protective equipment to prevent exposure during spraying and within the
4 hour*-period after spraying is completed is critical to eliminating the
health hazard. Once sensitization has occurred, a worker might not be
able work safely with spray foam insulation again.
Sprayers, sprayer helpers, and anyone else present during spraying
or within 4 hours* after spraying is complete: You must wear proper
Personal Protective Equipment (PPE) at all times during spray, including
full-body-coverage, chemical-protective clothing and a NIOSH-certified
respirator with fresh air supply. While spraying and for 4 hours* after
spraying is completed, no one must be allowed within 50 feet of the
sprayed foam without wearing this type of PPE at all times. Adequate
active, negative pressure ventilation (exhaust fans) of the job site must
be in place during spray and for 4 hours* after spray is complete.
For installations of low VOC products Icynene Classic Max and Icynene
ProSeal in the United States only, re-entry and re-occupancy of the
job site is permitted after 4 hours* provided that ventilation rates are
followed as recommended on this page.
Independent studies and third party toxicologist verification indicates
that when the prescribed ventilation rates and periods are followed,
Icynene spray foam insulation is safely cured.
Health & Safety
Certified Sprayer
The Evolution of Insulation™
Icynene Inc. 6747 Campobello Road
Mississauga, Ontario L5N 2L7 Canada
Ph: 1.800.758.7325 • ICYNENE.COM
SL-511 • Updated May 2015
WARNING
WEAR PROPER PERSONAL PROTECTIVE
EQUIPMENT AT ALL
TIMES ON PREMISES DURING SPRAYING AND WITHIN 24 HOURS AFTER SPRAY IS
COMPLETE
RE-ENTRY AND RE-OCCUPANCY PERIODS
Times based upon ventilating during and after a
spray application.
Ventilation Rate
(Air Changes
per Hour)
Re-entry
period for
sprayers,
helpers,
informed trade
workers and
contractors
Re-occupancy
period for all
others
At 0.3 ACH 24 hours 24 hours
At 1.0 ACH 12 hours*24 hours
At 10.0 ACH 4 hours*24 hours
At 40.0 ACH 4 hours*4 hours*
* Twelve (12) and four (4) hour re-entry for trades applies to all Icynene products sold in the United States. Four
(4) hour re-occupancy applies only to low VOC products
(Icynene Classic Max and Icynene ProSeal).
WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT AT ALL TIMES ON PREMISES DURING SPRAYING & WITHIN 4 HOURS* AFTER SPRAYING IS COMPLETE. *FOR APPLICATIONS OF LOW VOC ICYNENE CLASSIC MAX AND ICYNENE PROSEAL ONLY.
LowVOC