36 Complaints 2011-2014 1/18/2011 07:38 4135870350 SM.IMETAL PAGE 02/23
Revision pate:12-May-201 t
Product Name
Product Code
Product Class
Color
Manufacturer
Benjamin Moore&Co.
101 Paragon Drive
Montvale,NJ 07645
Phone: 201-573-9600
www.benjaminmoore.com
Hazardous Components
A
Benjamin Moore
Paints
Material Safety Data Sheet
SUPER SPEC EXTERIOR ALKYD PRIMER
176
SOLVENT THINNED PANT
All
Emergency Telephone Number(s)
CHEMTREC:800-424-9300
Revision Number. 1
Chemical Name
CAS-No
Weight%(max)
Limestone
1317-65-3
45
Stoddard solvent
615s31-3
15
Titanium diode
13463-87-7
15
Donates petroleum,nydmlreated fght
64742-47-8
10
Solvent rmpMha.petroleum,medium aliphatic
M742-88-7
5
Slfica,aystaarre
14808-80-7
0.5
Ethyl benzene
100-414
0.5
Emergency Overview
WARNING
Vapors may be irritating to eyes, nose,throat and lungs.May cause skin imitation and/or dermatitis.
Combustible material.
Rags,steel wool or waste soaked with this product may spontaneously catch fire it improperly discarded
kppearance liquid
Odor solvent
)SHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication
Standard(29 CFR 1910.1200).
Page 1/10
18/2011 07:30 4135870350
6-SUPER SPEC EXTERIOR ALKYD PRIMER
SHJMETAL PA(it 03/23
Revision Date:12-May-201 I
dentiai Health Effects
insipid Routes of Exposure
tuts Effects
Eyes
Skin
Inhalation
Ingestion
hronic Effects
Eye contact,skin contact and inhalation.
Contact wlh eyes may cause irritation.
May cause skin irritation ardor dermatitis_
High vapor I aerosol concentrations are inhaling to the eyes,nose,throat and lungs
and may cause headaches.doziness.drowsiness,unconsciousness,and other
central nervous system effects.
Ingestion may cause irritation to mucous membranes.Small amounts of Ns product
aspirated into the respiratory system doing ingestion or vomiting may Cause mild to
severe pulmonary injury.possibly progressing to death.
Avoid mpeated exposure
Conbns:Crystalline Silica which has been determined to be carcinogenic to humans
by IARC(1)when in respirable form.Risk of cancer depends on duration and level of
inhalation exposure to spray mist or dust from sanding the dried paint
es Section I1 for editions!Toxicological ismnaa'nn-
,ggravabd Medical Conditions None known
VMS Health:V FlammabiMy'.2 Reactivity 0 PPE: -
IMS Legend
-Minimal Hazard
-Slight Hazard
-Moderate Hazard
-Serious Hazard
-Severe Hazard
-Chronic Hazard
-Consult your supervisor or S.O.P.for'Specter
endling instructions.
kit The PPE sang hes intenNonally been kabda. Choose wproprials PPE Um twill protect maks/ees from the hreaeds the melevt wit pemw&
Meths actual name,cast&ono or use
:euam:HMISS MAWS are band on a 0-4 rating seals with 0 ropresereg nwv7wI haunts or Oa,and 4 npruswei'19 Suricanthazards orriay.
Wtjough HAMS&=Ono we not.nthed on Mab&a under 29 CFR 19111200,Me&spares les Moments provide Mal-H14Se ratings are le to
wed only N atiam$oe cosh a ray issiremented HUMS program by workers der hate teethed wproPaaS HIPS&reeking.Wefts a ngia►red
rade and service me&dine nAGA.HMSO rmieks nary be purchased exclusively horn J.J.War(800)327-696&
ieneral Advice
Eye Content
Skin Contact
If symptoms persist,cal a physician.Show this safely data sheet to the doctor in
ail endanee.
immediately thmh with plenty of water.After initial flushing,remove any contact
lenses and continue flushing for at bast 15 menses.Keep eye wide open while
rinsing.If symptoms persist,®I a physician.
Wash off immediately with soap and plenty of water removing all contaminated
clothes and shoes.If skin irritation persists,cal a physician.
Page 2/10
8/2011 07:30 4135870350
SMJMETAL Veit nute3
s-SUPER SPEC EXTERIOR ALKYD PRIMER Revision Maw 12-May-2011
halation
;ashen
Ass To Physician
ntection Of First-Alders
unable Extinguishing Media
Move to fresh air.If symptoms persist,call a physician.
It not breathing.Rive artificial respiration.Call a physician immediately.
Clean mouth with water and afterwards drink plenty of water.Do not induce vomNng
without medical advice.Never give anything by mouth to an unconscious person.
Consult a physician.
Treat symptomatically
Use personal protective equipment
Foam,dry powder or water.Use extinguishing measures
that are appropriate to local circumstances and the
surrounding environment.
roteclNe Equipment Mid Precautions For Firefighters any self-contained apparatus
maid IWNIOS (appred o
mor equivalent)
and full protective gear.
pacific Hazards Arising From The Chemical Combustible material Closed confreres may rupture if
exposed to fire or extreme heat.Keep product and empty
container away from Mat and sources of ignition.Thermal
decomposition can lead to release of irritating gases and
vapors.
iensttiviry To Mechanical impact
IensltNlry To Static Discharge
lash Point Data
Flash Point(aF)
Flash Point(°C)
Flash Point Method
dammabldy Limits In AY
Lower Explosion Limit
Upper Explosion Limit
YFPA Health: 1 Flarnmabifdy: 2
No
Yes
104
40
PMCC
Not available
Not arable
Instability:0 Special NotApplirable
IFPA Legend
I•Not Harnrlois
1-Sightly
-Moderate
i-High
1-Severe
The reaps assigned are only vggenrdMi9r.the owbecodemwbter has ulb,WB tetponerblities for NFPA radios winos 06 +ptem is used.
Addition&hA,rmtbn regadng the NFPA retina system v evmbble from the National The ProWiwr Agway(NFPA)at wwr.nipaera.
Page 3/10
3/2011 07:30 4135870350
I-SUPER SPEC EXTERIOR ALKYD PRIMER
SM 1METFIL
-put U7/C3
Revision Date:12-May-2011
menial Precautions
Blronmentat Precautions
Mods For Clean-Up
Use personal protedNe equipment Remove all sources of ignition.
Prevent further leakage or soakage if safe to do so.Do not allow material to
mntaminate ground water system.Prevent product from entering drains.Do not flush
into surface water or sanitary sewer system.Local authorities should be advised if
significant spillages cannot be contained.
Dam up.Soak up with inert absorbent material.Pict up and transfer to properly
labeled containers.Clean contaminated surface thoroughly.
her Information None known
ladling
wage
xposure Limits
Use only in area provided with appropriate exhaust ventilation.Do not breathe
vapors or spray mist.Wear personal protective equipment.Take precautionary
measures against static discharges.To avoid ignition of vapors by static electricity
discharge,all metal parts of the equipment must be grounded Keep away from open
flames,hot surfaces and sources of ignition.
Keep containers tightly dosed in a dry,cool and well-ventilated place.Keep away
from heat.Keep in properly labeled containers.
DANGER-Rags,steel wool or waste soaked with this product may spontaneously
catch fire if improperly discarded.Immo:atey after use place rags,steel wool or
waste kh a sealed water-filled metal container.
amnions Uomponenrs
ACGIII
OSHA
Chemical NamB
Limestone
N/E
15 mg/m'-TWA total
5 mg/m'-TWA
Stoddard solvent
100 ppm-TWA
2900 mg/m'-TWA
500 ppm-TWA
Titanium dioxide
10 mgle?-TWA
15 mg!m'-TWA total
Distillates, hydrotreated light
WE
WE
petroleum.
solvent naphtha, medium Slade
WE
N/E
petroleum,
Silica,crystalline
0.025 mg/m'-TWA
respirable - (10)/4X8102+2)mg'n?TWA
respirable - (250y(XSiD2+5)mood
TWA
WWI dust - (aoy(%Sio2*2)mg/n°TWA
Etel benzene
too ppm-TWA
125 ppm-STEL
100 ppm-TWA
435 mg/m'-TWA
spend
1CGIH-American Conference of Governmental Industrial Hygienists Exposure Limits
)SHA-Occupational Safety&Heath Administration Exposure Limits
4/E-Not Established
Page 4(10
87:30 4135870350
SMJMETAL
Revision Date:12-May-2011
'ER SPEC EXTERIOR ALKYD PRIMER
ing Measures Ensure adequate ventilation,especially in confined areas.
Prot dive Equipment
Safely glasses with side-Shields.
dPace Protection t on Lang sleeved clothing.Protective gloves.
in l a cry Pr n In operations where exposure limits are exceeded.use a NIOSH approved respirator
sPlralory ProtaCPq that has been selected by a teh]mirally qualified person n for ob areas, work r a NIOSH
conditions.When spraying the prodct or applying organic named
approved respirator specified for paint
Avoid contact with skin,eyes and clothing.Remove and wash O contaminated clothing
before reuse.Wash thoroughly after handling.
smcKS.
Measures
ranee
y(Ibsrgal)
le Gravity
liquid
solvent
11.9-12.1
IA-1.5
Not available
ally(eentistokes) Not available
nation Rate Not available
Pressure Not available
r Density Not available
70-50
r li 50-50
5so d ae 20-30
I I
Yolaiiss 40-50
Regulatory Limit(gill <350
ng Point(°P) 275
ng Point(°C) Not available
zing Point i°C Not available
zing Point Et) 104
ih Point(°C 40
ih Point( e) PMCC
Ili Point SiO'Method
Limit Not evadable
ter Expl
ter Explosion limit Not available
iemlral Stability
indigene To Avoid
compatible Materials
Stable under normal conditions.Hazardous polymerisation
does not occur.
Keep away from open flames,hot surfaces,static electricity
and sources of waken.
Incompatible with strong acids and bases and strong
oxidizing agents.
Page 51 10
1. 07:30 4135E70350
PER SPEC EXTERIOR ALKYD PRIMER
ass Decomposition Products
iMy Of Hazardous Reactions
SM3METAL
Revision Date: 12-May-2011
Thermal decomposition can lead to release of irritating
gases and vapors.
None under normal conditions of use.
roxiei
A lead to permanent brain and nervous system damage.
tea or misuse prolonged exposure concentrating and inhaling vapors may be harmful or fatal.
)tml misuse by deliberately
onent
tone
Oral:6,450 mg/kg(Rat) vendor data
tization:Na sensitizing effects known.
lard solvent
Oral:>5,000 mgikg(Rut)
I Dermal:>3160 manta (Rat)
Inhalation(Vapor):> mgIL
iium dioxide
Oral:>24000 mg/kg(Rat)
it Dermal> 10000 mg/m3 (Rabbit)
Inhalation(Dust):>622 mgfL (Rat,4 hr.)
hates. trolet hYdrotrealed light
D Oral:>5,000 mg/kg(Rat)
b i0 DeDemob>3,000 mg kg (Rabbit)
vent nit hM I_---,
, medium alt Katie
50 Oral:>6240 mg/kg(Rat)
50 Dermal.>3120 mgikg (Rabbit)
50 Inhalation(Vapor)::1400 ppm (Rat,4 hr.)
ice crystalline
150 Oral:500 mg/kg(Rat) vendor data
hvl benzene
)50 Oral:3500 rng/kg(Rat)
)50 Dermal:>5000 mu/kg (Rabbit)
X50 Inhalation(Vapor):55000 mg/m3(Rat,2 hr.)
ensitizBtion:No sensitizing effects known-
'hr nic Toxicity
iarcinogenicity ingredient as a carcinogen:
lie information below indicates whether each agency has listed any ng
Page 6110
07:30 4135E70350
:R SPEC EXTERIOR ALKYD PRIMER
Name
Beside
staline
cone
EM.3METAL
Revision Date:12-May-2011
determined to be carcinogenic to humans by IARC(1)when in respirable form pRiis of
irlde ends has been n and mist or dust from sanding
a ugh IARCs has duration and titanium of inhalation a np sibs ca to spray on
ugh IARC tress dassifed titanium tliozide as possibly carcinogenic to humans(2B),then summary concludes:'No
cant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound
let materials,such as paint'
-American w+
e°coI�industrial Hygienists
International Agency for
(Modal Toxi Program
-Occupational Safety
Heath Admin6lration
xkNy Effects
duet
Tox
rformabon available
to Toxic to A iodic Invertebrates
nformatinn available
rtes Toxic to _I--plants
information available
urrponent
ide 7 �tp Fish
annum dioxide
;50: >1000 mg&(Fathead Minnow-96 hr.)
hylbenzene
]60: 12.1 mgt(Fathead Minnow-96 hr.)
Page 7110
07:30 4135870350
SPEC EXTERUCK ALKYD PRIMER
e.., lnver0ebrates
1e
rglt(Daphnia magna-48 hr.)
'tv to Ards
5M.7ME1AL
Revision Date_124 ay-2011
molt(Green algae(me Bceoedosmus subspiratus),72 hrs.)
;posal Method
Dispose of in accordance with federal,state,and local regulations.Local
requirements may vary,consult your sanitation department or state-designated
environmental protection agency for more disposal options.
open Shipping Name Paint
rzard Class 3
UN1263
4-No lit
asking Group than
rtation(refer to 49CFR173.120(b)(2)for further Information).
the US this material may be redass`ted as a Combustible Liquid and is not regulated in containers d
19 gallons(450 titers)via surface transpo
Contact the prepare(for further information.
IATA
Contact the preparer for further Information.
national national inventories
id States TSCA
Ida DSL
feral Regulations
.A 311/312 hazardoodzatlon
Acute H ealth Hazard Yes
Yes
Chronic Health Hazard Yes
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard
Yes-All components are listed or exempt
Yes-Al components are listed or exempt
Page a110
07:30 413587 0350
SMJMEItrt
Revision Date:124MaY-2011
R SPEC EXTERIOR ALKYD PRIMER
I Of Title III of the Superiund Amendments and Reauthorization Act of 1986(SARA). This product contains a
r chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal
s, Pad 372:
CAS-No 0.5
mien)Name 100-41A
1 benzene rar for further
i product may contain Dace amounts of(other)SARA reportable chemicals Contact The propa
oration. HAPa see 41)CFR 61
r Act.Section 112 Hazardous Air Pollutants
iuct contains the following :
We'u1d%lmazl
CAS-NO 0.5
nyl bent Name .100-41�
nyl induce the prepares'for further lnmrrnaaon.
Ps product may contain trace amounts of(omen)HAPS rhemitats. Contact
Requlatior_IS
' P�
oduct may contain 6 small amounts of Materials know to the state o(Cald'omfa to cause cancer or reprodu
Wefahj 76�maxf
Right-to-Know
Chemical Name
tine
Stoddard solvent
-titanium dlovide
vent naphtha,petroleum
rnediuma9� atc
Sifra taaine
Eth benzene
ind
sted
Louislarla
00 .MEMO
,RNINGI If you scrape.sand,or remove old paint,you may release lead dust.LEAD IS TOXIC.EXPOSURE TO
approved ESPECIALLY SrconedleadLDREN. Clean)M)MEN DUST CAN CAUSE SERIOUS POWERS,SUCH AS DRAW DAMAGE,res tl le and CHILDREN.
e by p
Baton;you start,find out how to protect u euland.
)MEN SHOULD ALSO AVOID EXPOSURE.Wear a ROSH ap
tacit with a HEPA vacuum and a wet mop.
ninny lading the National Lead Information Hotline at 1$00.42f4-LEAD or log on to www. P
Page 9 110
07:30 4135870350
SMJMETaL
Revision Date:12-May-2011
t SPEC EXTERIOR ALKYD PRIMER
Product Stewardship Department
Benjamin Moore&Co.
360 Route 206-P.O.Box 4000
Flanders,NJ 07836
866-6981961
12-May-2011
late' Not evadable
iummary
Y
to be accurate as of the effective date shown above.
supplement to
satin is furnished ed wnmput warranty of kind.Employers should use Ni information only as a sup ment to
determination of suitability and completeness of
rmatla gathered fi ssr ed end Wrath t suitability a employees.Any 1y0 of this deb end
rmatir s e Bte by them and must to be in ac and the safety livable federal, provincial, and local laws and
curets to assure proper by the Ness be in accordance with applicable
Is roust� determined by the user to
w_ End of MSDS
Page 10 110
07:30 413587 0350
ere:Of-Jul-2010
SMJMtIPL_
Benjamin tMoore
Pain
Material Safety Data Sheet
Resistor%Number: I
lame
.lode
Class
BM FRESH START ALL PURPOSE 100%ACRYLIC PRIMER
H023
WATER THINNED PAINT
AU
Emerge.�f�7 IePte rs Nrimber(s
Surer CHE'MTREC:BOO-424-9300
t Moore&CO.
3gon Drive
3,NJ 07645
201.573-9600
ntaminmeore.cem
Emeruencr Over skin irritation and or dermatitis
Vapors may be irritating la eyes,nose,throat,and large. May
Odor little or no odor
rearance liquid
entlal Hem
ncipal Routes of Exposure
rite Effects
Eyes
Skin
Inhalation
Ingestion
drank Effects
Eye contact,skin contact and inhalation.
May cause slight irritation.
Substance may cause slght skin irritation. and diarrhea.May cause'vdtation of respiraloty tract.. vomiting Ingestion may cause gastrointestinal irritation,nausea,
Repeated contact may cause allergic reactions In very susceptible persons.
Page 1Ia
07:30 4135870350
SMSMETt1L
Revision Date:07Jul-2010
RESH START ALL PURPOSE 100%
RIMER
IT for addtlonal Toxico°9ied Of°mratron
d Medical Conditions None known
Health:1* Ffamma0rl ty:0 Reactivity:0 PPE: -
snit
Hazard
azare
e Harard
Hazard
Hazard
:Hazard
I your supervisor or S.O.P.tor"Seeder ppreswrc
vstuctirating has s hare dre herdrdsthe Meta'id
s i b been blank Choose appmPdata PPE the coy Prated onw Y're rnnmNS wrists.
ideal carnal coardians acak,wits 0 representing minimal hazards a Ads,awl 4 representing .Harts racksem
1910.1200.Benlardn Made B Co..tars chooser HMSO them. )ice
anly conjumain one i,Iem8P under 29 program who have received appropriate MSS&required mCA.Hnkdtnawd&3my ey�eztJsiuery from.1 J.KEkr f00B1�-B8a.
CMS®ratings we no!aade erN service mark Male ryPCA.1wAl�metensameY be purchased
d Advice
intact
:ontact
Rion
tion
s To Physician
No hazards which require special first aid measures.
Rinse ihofotighly with plenty of water for at least 15 minutes and consult a phy sician.
Wash off ingnediatety with soap and plenty of water removing all contaminated
clothes and shoes.
Move to fresh Sr.If symptoms persist.calla physician. ivan if
Clean mouth with water and afenvards drink plenty of water.Consult a phys
necessary.
Treat symptomatically
Use extinguishing measures that are appropriate to local
able Extinguishing Media Use and the surrounding environment.
,tective Equipment And Precautions For Firefighters pressurre-demand,MSHAI OSH(approved Of equivalent)
and full Protective gear. d to{v0.or extreme
Closed containers may rupture if exposed
Hazards Arcing From The Chemical Closed heat.
:nsitivity To Mechanical Impact
No
Page 218
77:30 4135570356
tESH START ALL PURPOSE 100%
IMER
o Static Discharge
Data
Point CT)
Point(1C)
Point Method
ty Limits In Air
e Explosion Limit
it Explosion Limit
Health; 1
end
ardous
SMJMLIHL
Revision Date:07-Jul-2010
No
Not applicable
Not applicable
Not applicable
Not applicable
Nol applicable
Flammability: 0
Instability:0 Special:Not Applicable
be
assigned by eerdennn Mourn&Go,ere rte
only suggested ratings.lire conhertamplo;ar has unlearn res0onsbdiues far NFPA ratings when
ie usMt Fie Protection Agency(NFPA)at sww nrpacrg
*matron regarding the NFPA rating gygkm k avarYabk ham the Netionel
al Precautions
.mental Precautions
is For Clean-Up
Information
Avoid contact with skin,eyes and clothing.Ensure adequate ventilation.
Prevent further leakage or spillage if safe to do so.
Soak up with inert absorbent material.Sweep up and shovel into suitable containers
for disposal.
None known
- . . ... wnh skin,eyes and clothing.Avoid breathing vapors,spray mists or
of insufficient ventilation,wear suitable respiratory equipment.
Avoid contact ling sanding dust.In case of children.Keep container tightly closed. Keep out of the reach
ge
;sure Limits
Page 3I0
07:30 413587 0350
:RESH START ALL PURPOSE 100%
RIMER
SM.3METPL
Revision Date:07-Jul-2010
tedean Conference of GOvernmental lydustne Hygien%Exposure uses
;uPationat safety&Heat%Administration Exposure
etabIlsried
lug Measures
Prot..a' 6outpmeot
dime Protection
p-h ncWncW
in Protection
spiratoN protection
Measures
Ensure adequate ventilation,especially in confined areas.
Safety glasses with side-shields.
Proteciw gloves and impervious clothing.
In case of insufficient ui equipment.
vacillation wear suitable resptm a iory 9 P
d tact with skin eyes and clothing Reprove and wash contaminated clothing
Avoi
eon
before re-use.`Nash thoroughly after handling.
y(Ihalgal(
tc Gravity
ration Rate
Pressure
•Density
Solids
e Solids
}Volatites
Ai Volatiles
Regulatory Limit(gIL)
ng Point(°P)
ng Point(•C)
zing Point r9
zing Point 1°C)
It Point(°F)
Point l°C)
;h Point Method
rer Explosion Limit
war Explosion Limit
liquid
1pie or no odor
9.5-10.3
113-1-24
Not available
Not available
Not available
Not available
40.50
30-40
50-60
60-70
<100
212
100
32
0
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
temicat Stab Mg
,nditians To Avoid
Stable under normal conditions.
Prevent from freezing
page 418
SMJMElut_
07:30 4135870358
Revision Date:07-Jul-2010
:RESH START ALL PURPOSE 100%
RIMER
No materials to be especially mentioned.
pie Materials
Of Hazardous Rion Products
None under normal use.
None under normal conditions of use.
p(Hamrdous Reactions
rtci
atian available
ant
dioxide
al:>24000 mg/kg(Rat)
smal:>10000 mgim' (Rabbit)
,elation(Dust):>6.62 mg/L (Rat,4 Iv.)
ref.>5000 mg/kg(Rat)
c Toxici
,mi
ain indicates whether each agency nas listed any ingredient as a carcinogen:
bmlation below
urn dioxide
as possibly carcinogenic to humans(2R)•their summary concludes:`No
hough iARD has to titanium titanium dioxide P� r during the use of products in which titanium dioxide is bound
�nficant exposure to titanium di0zde is thought to occur
materials.such ea Paint
tit conference nference of Governmental industrial HYtlionists
-Iational Toxic Agency
Toxicity for Researoh on Cancer
-National Safep�a Health Administration
W-OCCUPamon
lox-o ty Effects
•oduct
Page 518
07.30 413587 0350
RESH START ALL PURPOSE 100%
RIMER
SMJMEIHL
Revislon Date;07Ju1-2010
i
i on n available
Fish
wi t0 uariclmrertebrates
lion available
WI lv to Aquatic Plants
rtjun available
tent
xicRy to Fish
dioxide
IOW mgil(Fathead Minnow-96 hr.)
axis' t Wuat iclnvertabretes
nation available
Irlty to netic Plants
nation available
Disposal Method
Dispose of in accordance with federal,state,and local regulations Dry,empty
containers may be recycled in a can recycling progrw LOCSI requirements may
vary consult your sanitation department or state-designated environmental
protection agency for more disposal options.
tl IATA
G!IMO
Not regulated
Not regulated
Not regulated
emotional Inventories
ited States TSCA
nada DSL
Yes-Alt components are fisted or exempt.
No-Not all of the components are listed.
One or more component is lured an NDSL.
Page 6 I 8
07:30 41350703E0
,RESH START ALL PURPOSE 100%
RIMER
SM3METAL
Revision Date:07-Jut-2010
tegutations
912 hazardous Gate orization
Health Hazard
inic Health Hazard
Hazard Hazard
den Release of Pressure
dive Hazard
of Title Ill of the Supertund Amendments and Reauthorization Act at 1986(SA This product COraafrrsa
3
or chemicals which are subiectto the reporting requirements of the Act and Tale 40 of the Code of Federal
13
nus, Pad 372:
is product may contain trace amounts of(Sr)SARA reportable chemicals. Contact Benjamin Moore&Co.for
therintonnalion- 40 CFR 61
Hazardous Air Pollutants HAP S see
,ir duct c.Section 112 Haze ryPPS.
,duct mntams the tollowing &Co,for further
his product may contain trace amounts of(other)HAPS chemicals Contact Benjamin Moore
'formation
No
Yes
No
No
No
Lte_AulatiPILs
rola Proposition 65 reproductive
induct may contain small amounts of materials known to the state of California to cause cancer or reprod
end
isted
\RNINGI If you scrape,sand,or remove old paint,you may release lead dust.LEAD IS TOXIC.EXPOSURE TO
rSP ESPECIALLY
to control IN CHILDREN.
H exposure-Clean A
Before you sled,find out now W Protect r le and your family
AD MEN SHOULD ALSO SO AVOID EXPOSURE.W�a NIOSBRAIN PPro"ed respirator IN n�la REN.PREGNANT up
,thud/with a HEPA l Lead vacuum and a wet mop• on to vrwc.eoursel
,ntaCting the National Lea Information Hotline at 1-800-424-LEAD or -y-
Page 718
SMJMEIAL
07:30 4135870350
Revision Date:07-Jul-2010
RESH START ALL PURPOSE 100%
RIMER
Product Stewardship Department
Benjamin Moore P.O.soz 4000
360 Route 206'
Flanders,NJ 07836
866.690-1961
07-Jul-2010
)Me: Not available
Summary
good faith and believed to be accurate as of the anecave�"�e to
m▪ alls contained herein is presented warranty ins Mod. Employers should use this information only as a o{information ent
__ independent determination of suitability and completeness this data mates to as sure drruse of these materials tape and health of employees:is
uu of there e In and Once applicable federal, provincial, and local laws and
uwices to ass ermPmhmePd by time user m be In accordance
• must be determined
ns' End of MSDS
Page BIB
SMJMEIAL
37:30 4135270350
M A T E R I A L S A F E T Y D A T A S H E E T Rev. 0613
For Coating, Resins, and Related Materials NPCA 1-09
BENJAMIN & Ca
EmerrggeencA24Tele0h ne NoNo.
51 CHEW M00RE S CO.
51 CHESTNUT RIDGE AD
MONTVALE, NJ 07675 Rev Date In:oATat ion Telephone O.
Date
Prepared La OS-07-00 201-S73-9600
01--1°.19--01 up-t0-date SOS
information o iTml
FOT Ch¢ ebsi P- ben7aminmoore.com/msds/g most
.. Nini. _______
please visit our website _____
_ _ - PRODUCT ID
--—-
SECTION I
♦` HM-S CODE "
HEALTH: 2'
FLAMMAAILITY: 2
)DUCT`: MOL, nM06 REACTIVITY: 0
CLASS: SOLVENT THINNED PAINT REACTIVITY:
PITY:
NAME: ALKYD METAL PRIMER
COLOR: ALL 4* SARA TITLE 312 "
ACUTE: Y CHRONIC: Y FIRE: Y PRESSURE: N REACTIVIT Y: N
x a complete description of HMIS and an explanation of the PERSONAL PROT:
code a little n can be any capital letter of the
)de, see Section %x
--- In the PRODUCT
1phabet except P or D. ____ __ ____
SECTION TI HAZAR000S INGREDIENTS - - - - - __
- ?EL --
—__—___ STEL CE+L MM H9
TLV ---'----
INGREDIENT --_
--- SARA MAX 6 CAS I _______ ________
_____ ___________
Ethyl Benzene
7 .1 000100-41-9 100 ppm 100 ppm 125 ppm
N/E .a 2
zee
-------__ _
Stoddard Solvent
100 ppm 100 ppm --'-
N
N 30.9 008052-41-3 _____________________
Csys .1 01e 1 mg/M3 .1 mg/M3 N/E
N/A
Silica, 1 019808-60-7
Iron Oxide
6 mg/M3 10 mg/M3 N/E Hit N/A
Y N 7,2 001332-37-2 __
10 mg/M3 15 m9/M3 NIL N/E__________ .-
zinc Phosphate _ _-
I Y 0.1 707779-90-0 _____
_ N/E N/A
Aluminum -----ha00>]99-30-]
10 mg/M3 N/E
______.-_ ___ ___________
YN _________
__ __ ___ N/E N/E N/A
Male 2 m9/M3 2 mg/M5 -- N/E _- - _
Nip Y N 41.4 01990>-9 - ______-
_________________________ 2.0 @ 613
----- Ethyl E`etD0009 ppm _—
.2 000096-29-7 0.1 p
Y N N%________-
titanium Dioxide 10 me/M3 10 mg/M3 N/E
y N i3.9 713963-67->
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:M06,113406
Page^.
N/E N/A
:vide 10 mg/M3 10 ag/M3 N/E ________==y==*
1,7 001319-13-2
reported carcinogens cr suspected
This x== coma =,=one=or=more=rep+= _Z in the other _suits
This s which=are nots IARC or OSHA
-2
which are noted NIP, xx++++µTµ4.=++x++=rx..wµw=...r«..µ.
wended column-
This product contains pigments which may
sanding, or grinding' Co the State of
vpr du abrasive co contain t blasting, materials known - -
ctai small amounts of
xoduCtive harm
product --- cancer and --- - ___-- - -
£ornia to cause
SECTION III -------- DATA -_
PHYSICAL------------------------------------- ----- -----------------
-- ---- 0.0 W^/GL: 10.6 to 12.0 $'✓OL/VOL° 41.5
Pa4e to p 53.6
L RANGE: 0.0 N S.D.S for M06, nM06 _
VAp3R DENSITY HEAVIER THAN AIR
SLOWER THAN ETHER__________________
,FGRATION RATE: _____ _____
-___-------_ AND EXPLOSION HAZARD DATA - _ _
SECTION -- FIRE --_- --
__ __—__S__
D.T. FLAMMABILITY CLASS.: COMBOSTIBLE FLASH POINT: 107 E YvC
L $+ 0.0
I EG
TTNGCI
CO2 DRY CHEMICAL WATER FOG
MDDIX: SOO
IOSCAL FIRE AND EXPLOSION HAZARDS:
when Product borne. fire-
La• se gases may farm if exposed to extreme heat Or
1.08ed LOIRE FIG may burst p aID[pa.
oci eL FIRE contain s with Use self-contained breathing app
col exposed containers with water- Use self-contained breathing_--_
o not use water stream on bo=ning liquid.
pparatus- -^_ _- ______—
_ _ ___—__
___- -_ SECTION V HEALTH HAZARD DATA _--__---
g$;ECTS OF OVEREXPOSURE - ACUTE: _-
May affect the brain or nervous system
dizziness,- Harmful i y inhaled.
cau• sing dzziness, headache or nausea.
- Causes eye irritation. product have the
Contact skin this p
Contact - Causes skin ingredients contained in rodu to cause
o be absorbed through ug the akin in sufficient quantities to
VIII) .au
Skin Absorption absorbed through and Use Information (Section
capacity to be ngesti
toxicity. See Safe Ha and nervous system
systenfc - th2 digestive tract Aspiration
Irritation of ticn and fatigue) . vomiting and or Ingestion loss of coordination swallowing
dizziness enter lungs during
(d.towaipe99• can n
cause - This laMMa bon and damage. _
cause lung OVE EXPOC - CHRONIC: ruined to be carcinogenic
Contain OF Oystalline E which has been date depends on
when in respirable form. Risk of cancer P
Contains: Crystalline silica from sanding the dried
TARE exposure to dust
to humans (1) by lAR stew. damage
duration and level of inhalation ezp
or spray mist. permanent brain and nervous system in
paint to associated p among persons engaged and
with sated. prolonged overexposure to solvents concentrating nga9
repeated, pre. Ina ntional deliberately wits repeat Intentional misuse by etel. ns l2b) -
the laimihe trade. be harmful or f or h'ama
inhaling the contents may
as possibly carcinogenic f
IED1 has classified Ethyl Benzene
MEpZCA1 CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE:
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37:20 4135070350
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Y'.MB6,nMO6
expected when used in accordance with Safe Handling and Use
nIatlon (Section dust xnbalation may cause lung danie9e'•
Stem inn
'at:on statement: Sanding which has been identified as a
atns Mania Ethyl R care a (HERO Currently, MEND is not listed as a
Octal carcinogen liver °IpkC,oNTP Or OSHA. INGESTION
Otyay UTE (SnoOFn Ny DERMAL INHALATION
iARY ROUTE(51 OF ENTRY: call physician.
lGENCY AND a FIRST AID PROCEDURES
dar • maintain breathing,
RCoitn t Remove eloc. hazard andawater. o£ water. Call physician
a Contact -Flush Remove with soap with large amounts
Flush imitn2 glasse water to dilute.
Cei-Ofl or 2 glasses of NaTion - Drink 1 h sician-
Cal: p Y
NOT induce vomiting, __ __ __--------
SECTION VI REACTIVITY DATA
__ _
ABILITY: STABLE - --HAZARDOUS POLYMERIZATION WILL NOT OCCUR
ZARDOUS DECOMPOSITION PRODUCTS: of vapors up
ruing may TO AVOID carbon dioXide and carbon
and build foreseeable.
sALS TO top - _ _
NUITIONS TO AYOI D: _ ___
ICOMPATAHI LITY (MATERIALS TO AYOI JI � None reasonably
-- SECTION VII SPILL OR LEAK PROCEDURE
vapors. Use non sparking
TENS
0v TO a 1 TAKEN IN CASE MATERIAL Ii breathing OR residue with Fullers eking.
.em°ve o e sources of als too c. Avoid "�Ir Absortlg
.cols to reru=n materials to container.
DISTE DISPOSAL METHOD:
state and :edera_
procedures in compliance with. local,
incinerate sealed containers.
------ i--- p not incin ---
regulations. ➢o ____ —_-
_________________ HANDLING AND USE INFORMATT_ON_____ ___
A-- -
____________ SECTION VIII 5 _
_ -�—"��------^� f---- - -- -- ----- -- roved by NIOSH for
WEaPIRApOoY rROTECTION: - Page 3
Wear a properly fitted vapoxlpartsculaie respirator approved
fox M06, nMO6 and until all vapors and
Ming .S r sanding -
ints during d.application ° aces or in situations where is
Tie .itS Pa confined spaces roper respirator
mist are exhausted. ical� 0t �� proper
respirator approved by
spray spray r operations are eSS supplied air
sp pfd a pos-tive-pre55uxe,
Oct possible,
NIOSH- ION. below T.L.V. and L.E.L.
Adequate working atmosphere HEChanled7. exbauet
Adequate to ma data and concentrations)
(aye eere. II for inorediedt sources.
be required in only confined ea awn from ignition
may noo in area away loves are required.
EIS
Discharge exhaust impermeable gloves with side shields.
splash goggles or safety 9 roteet Skin.tO yRDTECT IV£ GLOVES: solvent
EIS PROTECTION : A smoking
OTHER PROTECTIVE EQUIPMENT:before reuse.ad Wash hands betOre eating,
HYGIENIC PRACTICES:
Remove and wash clothing
the Washroom. _ __
_ _ __________________________
or using tb°
SECTION I% SPECIAL ------TIONE _--_ _—----
PRECAUTIONS TO BE TAKEN fIN rom H NDLINGnA ElSTORA�
Combustible - Keep away
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I:M06.oMO6
p tECA UTIONC •
: -y with adequate ventilation. A
voi
d pro
longed contact with th skin and
nd
:hind of vapor spray mist or s anding dusi.
• container afte r each use. Keep out of reach of children. to not
internally.
__________________
SECTION R%
•--------------------------------------------------------
az-- Identification System) (A) NPCA
Communications System as re4aired by
PMTS (Hazardous Materials _ a compliant hazardous
is a FR 1910.12 workplace Information Hazard establishing
CFR 1 program ) - M va le from:
N. (29 RMIo is available La Division
:nunicat ion program using Inc. abelmas>er
American ulaski Rd.,Co., IL 60646
5724 N. Pulaski Rd.. 2hicago,
1-800-621-5808 Moore only suggested -stings%
& Co. are > y eels rating rat wbexe
Old contractor/employer has Benjamin ate_e - ir for
. ratings assigned ultimate resPOns;bi- Y
z AROMAS, ct TECTi loyex has
is system is used. left blank on nenjamin Moore s Co. MRCS's
• and the workplace ventilation-
Rit de efl on ap This code is
on secbX o€ this MSnS before deciding on
it depands on aPPlicati Cedes
Sections "_1 throven I% o work. There are
ease read equipment hich and beginning Labelm33tei.
seems ate protective can be obtained from
this section which toxic chemical listed in SectiOn SS
sellable her least one 313 0�
contains at requirements of section q0 CPR 372.
his product reporting 1986 and 4 - ______--
• ect to the Right-To-Know Act o£
hat is st-- and --------- ------_ _
rergeacy Planning __ _ _____
_-- DISCLAIMER _ _
- _- r - -is resented in good faith and believed
s
affective date shown above• This information i
the information contained herein p Employers should use this
Of any kind. gathered by them and
to he accurate as of the rd by
Of
furnished withoutawarranty a lement to other inSOrmati and completeness,
mpY of suitability end
infcrmationn from ended determination to asn proper use of these materials
must make P - this data and information
information from alts sources to essurA P use o= applicable able federal,
must b and health of employees. y rdance with PP
fined by the user no be in acco
the safety
must be determined and regulations. or Diner means may
state and local laws paint by sanding.
scraping means
a Or fumes
of old P lead. EaOOSUte to lead women.
mayc : Removal fumes which contain especially in children of pregnant awe e .or
Contrail dust enon health effects, hazardous substances requires Muse
may cause adverse to lead t, other fitted respirator 1 or
exposure unt, such as a
Controlling P For additional information.
f proper protective tqunPm nt and cleanup- g00-LEAD-FYI.
approved) and proper containment Rotline at 1-
contact the VREPA/Lead information
f
,plainant: 7n
NATURE OF COMPLAINT: Ri andY v-) e
6 i
Ben Wood
Thursday, November 10, 2011 1:18 PM
Ed Smith
FW: Ralph's and funny smells
:he message. I have not written up a formal complaint yet but I will and will enter
1.
-t with having a conversation about their general business practices to get a handle
they are doing and what chemicals might be used. Then ask for any M5D5 sheets or any
ated compliance reporting. Also of course observe for any subjective smells when you
the neighborhood. As with the casket company it probably will be necessary to figure
the smells are consistent at certain times which could lead to knowing which business
es could be the cause of the smells. And also make note of any adjacent businesses
so could be the cause. Thanks. Ben
•iginal Message mail COT]
Tandy Gerry [mailto:mandygerry @ g
Jednesday, November 09, 2011 7:54 PM
i Wood
t: Ralph' s and funny smells
Rkdµ's - S"a"to - 5-. 5
ust copying the e-mail I sent to Owen. Happy to provide more details if it helps.
is an issue that I have been simmering on for sometime. I was just outside raking in
d industriald parkoneareus. Itn smellseveryw paint fumy fumy coming alc the
over in
cl ud emanating
talph's as well.
hey are zned le t
the toxico smellsranddgaseousrcloclouds are too healthy for l
anyone be can't
breathing.
leas?"
s for any help.
, 011i(� Entered By: �
Geo Tracking #:tasct1c —
SEPTIC HOARDING—
WATER/SEWER� HOUSING_ NAIL SALONS
SMOKE POOLS_
NUISANCE� ODOR
BODYART OTHER
Date Entered: u ' ro i)4
flt-2 k S TiU y
,IPLAINT INFORMATION:
iplaint Location:
are of Complaint:
SW t'tv& 5'1'Q.EE�
Date of Complaint:yL/Li
Child Under 6: Y/N
Animals:
YIN
)MPLAINTANT'S ORMATION:
nmplainantiOccupant's Name:
maplainant/Occupant's Address:
WNER'S INFORMATION:
Iwner'sName:
'roperty MgrJLL:
Complaint Unfounded:
Conditions Found:
�1
- - �Telephone# ( �-_66 Al
Alternate# ( )_—.–
Address:
Address:
Telephone#( )_.-
Alternate# ( )
Signature of Inspecting Officer
Da t/Time of Inspection