296 Chlorine Residual Results ENVIRONMENTAL LETTER OF TRgNSMI'
COMPLIANCE SERVICES, INC.
588 Silver Street ioe rvo
AGAWAM, MASSACHUSETTS 01001 DATE
April 26,2006 I 01-2013
(4131789-3530 "ATTENTION
Mr.Ernest Mathieu
TO Office of the Board of Health Pro Corporation-PMC
Puchalski Municipal Building 296 Nonotuck Street
212 Main Street Florence,MA 01060
Northampton,MA 01060
Via Mail Type: Hand Delivery by:
Regular n 2-Day Overnight Certified kd
WE ARE SENDING YOU ❑ Attached ❑ Under separate cover via the following items
❑ Shop drawings ❑ Prints ❑
Plans ❑ Samples ❑ Specification
❑ Copy of letter ❑ Change order ❑
COPIES DATE No. DESCRIPTION
1 4/26/06 Chlorine Residual Results for 11/8/2005,2/3/2006,and 4/7/2006
THESE ARE TRANSMITTED as checked below:
❑ For approval ❑ Approved as submitted ❑ Resubmit copies for a
® For your use ❑ Approved as noted ❑ Submit copies for di:
❑ As requested ❑ Returned for corrections ❑ Return corrected print
El
review and comment ®
Required Discharge Monitoring Reports
❑ FOR BIDS DUE 19 ❑ PRINTS RETURNED AFTER LOAN TC
REMARKS Should you have any questions,please do not hesitateto contact this office.
COPY TO SIGNED:
eu xmitofm If enclosures are not as noted, kindly notify us at once.
FROM SPECTRUM ANALYTICAL (THU)11 17 2005 16 :49/ST. 15 :47/N0. 55152
Report Date: Final Report
17-Nov-05 1417 0 Re-Issued Report
❑ Revised Report
SPECTRUM ANALYTICAL,INC.
Featuring
RANIBALTECHNOLOGY
Laboratory Report '
Environmental Compliance Services
588 Silver Street Project: Pro Corporation-PMC,Florence,MA
Agawam,MA 01001 Project X: 14991.00.07
Attn:John Siedel
Laboratory II) Client Sample ID Matrix Date Sampled Date Receive
SA36869-01 003A-I Waste Water 08-Nov-05 07:47 08-Nov-05 15:
SA36869-02 003A-2 Waste Water 08-Nov-05 09:46 08-Nov-05 15:
SA36869-03 003A-3 Waste Water 08-Nov-05 11:49 08-Nov-05 15:
5A36869-04 003A-4 Waste Water Os-Nov-U5 13:54 08-Nov-05 15:
SA36869-05 004A-1 Waste Water OS-Nov-05 07:44 OS-Nov-0515:
SA36869-06 004A-2 Waste Water 08-Nov-05 09:43 08-Nov-05 15:
SA36869-07 004A-3 Waste Water 08-Nov-05 11:45 O8-Nov-05 15:
SA36869-08 004A-4 Waste Water O8-Nov-05 13:50 08-Nov-05 15:
1 attest that the information contained within the report has been reviewed for accuracy and checked against the quality control
requirements for each method. All applicable NELAC requirements have been met.
Please note that this report contains 4 pages of analytical data plus Chain of Custody document(s).
This report may not be reproduced,except in full,without written approval from Spectrum Analytical,Inc.
Massachusetts Certification#M-MA138/MA7110 ori d y:
Florida E #PH-0777
Florida#E87600/E87936
Maine X MA138 fib*
New Hampshire#25382972
New York#11393/11840
Rhode Island#98 H ib I .Ta h,Ph.D.
USDA#S-51435 President/Laboratory Director
Vermont# VT-11393
Spectrum Analytical, Inc. is a NELAC accredited laboratory organization and meets NELAC testing standards. Use of the NI
logo however does not insure that Spectrum is currently accredited for the specific method indicated. Please refer to our"Qs
webpage at www,spectrum-analytical.com for a fdl listing of our current certifications.
ENVIRONMENTAL ANALYSES
I I Almgrcn Drive•Agawam,Massachusetts 011111.Operational Building&Sample Receiving
830 Silver Streets Agawam,Massachusetts 01001•Administrative Offices,Volatile&Air Deparlmenu Page
1-800789-9115.413-789-9018•Fax 413-789-0076
FROM SPECTRUM ANALYTICAL (THU) 11 17 2005 16:49/ST. 16:47/N0. 551U2i
Sturmle Identification Client Project h' Matrix Collection Date/Time. Receive
003A-1 14991.00.07 Waste Water 08-Nov-05 07:47 08-Nov-1
SA36869-01
CAS No. Amdyte(r) Rauh •RDUUnIIS Dilation Method Ref Prepared Analyzed Batch Analy
General Chemistry Parameters 1p Hach 8167 08-Nov-05 08•NOV•OS 5110534 ES
nexws Total Residual Chlorine 1.06 0.200 mg/1 1730
Sample Identification '
Client Project ft Matrix Collection Date(1'ime Receiv
0034-2 14991,00.07 Waste Water 08-Nov-0509:46 O8-Nov.
SA36869-02
CAS No. Anaryte(s) Rauh •RDUUnits Dilution Method Ref. Prepared Analyzed Batch Anal)
General Chemistry Parameters 10 Hach 8167 O8-NOVAS 6x.NOVAS 5110534 p.S
mssa•s Total Rasidud Chlorine 1.55 0.200 mg/1 17:30
Sample Identification Client Project# Matrix Collection Date/Time Receiv
0034-3 14991.00.07 Waste Water 08-Nov-05 11:49 08-Nov
$A36869.03
CAS No. AnalyteD) Resat •RDUUMa DIfuOOn Method Ref. Prepared Analyzed gawk Anal
General Chemistry Parameters
na2d0-5 Total Residual Chlorine 1.68 0.200 mg/1 10 Hach 8167 08-Nov-05- 08-Nov-05 5110534 U.
$ample Identification Client Project U Matrix Collection Date/Time Recei'
003A-4 14991.00.07 Waste Water O8-Nov-05 13:54 08-No'
SA36869-04
CAS No. Analyle(a) Rauh •RDUUnite Dilution Method Ref Prepared Analyzed Batch Ana
General Chemistry Parameters
7782•50.5 Total Residual Chlorine 1.53 0.200 mgtl 10 Hash 8167 08-Nov-05 0 08-Nov-05 5110534 E
Sample Identification Client Project 0 Matrix Collection Date/Time Recei
004A-1 14991.00.07 Waste Water 08-Nov-0507:44 08-No
SA36869-05
LAS No. Analyte(s) Reath •RDUUnhs Ddadan Method Ref. Prepared Analyzed Batch Ani
General Chemistry Parameters 10 Hach alb] 0%-Nov-US Oa-Nov-0S SI If1530
nrzsO-s Total Residual Chlorine 1.08 0.200 mg/I 10
Sample Identification Client Project g M rix Collection Date?ime Rece
0044-2 14991.00.07 Waste Water 08-Nov-05 09:43 08-Ni
SA36869.06'
CAS No. Aaalyte4) Rauh •RDUUniis Dilution Method Ref. Prepared Analyzed Batch An
General Chemistry Parameter,
77111-5o-5 Total Resides)Chlorine 1.64 0.200 mg/I 10 Hach 8167 08IN v-5 08-Nov-05 5110534
7:30
This laboratory report Is not rand without an authorized signature on the cover page.
•Reportable Deleolion limit BRL-Below Reporting Limit Pa[
FROM SPECTRUM ANALYTICAL (THU) 11 17 2005 16:40/ST. 15:47/N0. 55102
sand?Idcntincation Client Protect 4 !Mirk Collection Date/Time Receive
(104A-3 14991.00.07 Waste Water 08-Nov-05 11:45 08-Nov.
SA36869-07
CAS No. Analyte(s) Result •RDUDnhs Dilution Method Ref Prepared Analyzed Batch Anal)
General Chemistry Parameters 160 02W mpJl
77040.5 Total Residual Chlorine 10 Hach 8167 08-Nov-05 08-Nov-05 5110534 as
17:30
Sample Identification Client Project 4 Matrix Collection DatetTime Remy
004A-4 14991.00.07 Waste Water 08-Nov-05 13:50 08-Nov
SA36869-08
CAS No. Artdyte(s) Result •RDUTInIa Dilation Method Ref. Prepared Analyzed Batth Anal
General Chemistry Parameters
778240-5 Total Residual Chlorine 1.60 0.500 ins/1 25 Rich 8167 08"ov-05 08-Nov-05 5110534 E8
This laboratory report is nor valid without an authorized signature on the rover page.
4 Reportable Detection Limit BRL=Below Reporting Limit Rai
FROM SPECTRUM ANALYTICAL (THU) 11 17 2005 16:49/S`. 16:447/N0. 55102
Notes and Definitions
BRL Below Reporting Limit-Analyze NOT DETECTED at or above the reporting limit
dry Sample results reported on a dry weight basis
NR Not Reported
RPD Relative Percent Difference
A plus sign(+)in the Method Reference column indicates the method is not accredited by NELAC.
Laboratory Control Sample(LCS): A known matrix spiked with compound(s)representative of the target analytes,which is r
document laboratory performance.
Matrix Duplicate: An infra-laboratory split sample which is used to document the precision ofa method in a given sample mr
Matrix Spike: An aliquot ofa sample spiked with a known concentration of target analyte(s). The spiking occurs prior to sa
preparation and analysis. A matrix spike is used to document the bias ofa method in a given sample matrix.
Method Blank: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sample
processing. The method blank should be carried through the complete sample preparation and analytical procedure. The me
blank is used to document contamination resulting from the analytical process.
Method Detection Limit(MDL): The minimum concentration ofa substance that can be measured and reported with 99%
confidence that the analyte concentration is greater than zero and is determined from analysis ofa sample in a given matrix t;
containing the analyte.
Reportable Detection Limit(RDL): The lowest concentration that can be reliably achieved within specified limits of precish
accuracy during routine laboratory operating conditions.For many analytes the ROL analyte concentration is selected as the
non-zero standard in the calibration curve.While the RDL is approximately 5 to 10 times the MDL,the RDL for each sample
into account the sample volume/weight,extraci/digestate volume,cleanup procedures and,if applicable,dry weight correctic
Sample RDLs are highly mauix-dependent.
Surroeate: An organic compound which is similar to the target analyte(s)in chemical composition and behavior in the anal;
process,but which is not normally found in environmental samples. These compounds arc spiked into all blanks.standards,
Validated by:
Hanibal C.Tayeh,Ph.D.
lime O'Connor
This laboratory report is not valid without as authorized signature oa the rover page.
*Reportable Detection Limit Sit!.=Below Reporting Limit Pug
UHA1N Vr Luo 1 VL T tt r•L,V[tl-r All TATS subject to laboratory approval.
in
in y". Min.24-hour notification needed for rushes.
sr[crapw ANALYTIC/047.C. Page_1_of�— • Samples disposed of after 60 days unless
in rev,ea otherwise inskuclxd.
\ N!t)I DAL TCOOOLUG\'
Report TO: D 5 5` k� Invoice To:
ECS llaswn Project No.: IN44f.00,d7
-- - EIS Site Site Name:_ieo tc+epor4lro>,N
ir
Location: rio['SA1(�C-E Stolz:
o Project Mgr.: 3-01-,,i at.
o1'..I 9APL P.O.No.: RQN: STD
Sampler(s): TOM I,yp.J
- 1-NarS2Or 241C1 3=H;SO4 4=HNO; 5=NaOH 6-Ascorbic Acid QA Reporting Notes:
- ?
o I =CHIOH 8=NaliSO4 9=
ZCE 10- Containers: Analyses: (u5«kifneeded)
chi
State specific reposing standards
D14 Drinking Water GIV=Gmundnacer WW=Wastewater s a. I If applicable.please list tdo 4:
C OiI SW=Surface Water SO=Sail SL=Sludge A=Air z =ix, r
X1= X2= XJ=_ _ 7 C ❑Procldc MCP CAM Report
;j a• Were all field QC requirements met
Grab C=Composite e b k Z > Q C: E. 1 as pa MADEP CAM Section 2.0?
p nYrs ❑No
-1� Lab Id: Sample Id: Dart: Time: i y° _ u (Respome regmredf CAM report)
.,0%R—/0ys)) oo3A-I Is/%/o5 797 (. taw 9 I //<
_Oa,_ Oo3R-1 11/6105 9:4 6 ' 9 ) X
0o3R-3 11154/os _ 1149 U ww 9 I i
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O) et R-3 - 111'055 1(:45- G ww 9 1 x- I oo M-'1 II/g/os 150 G tow 9 I X
1
Relinquished by: evened by: Date: Time:
U 1• '14 Fax results when available lo(h{13 ) 'CS`a776AA O rJ! {i�5 jy�
- ❑E-mail to _ RRRLL Litt����4L,,((�/��llll����QQQf L I II U S
N• EDD Format !!
LL• Condition upon receipt: flied D Ambient ❑°C
11 Almgren Dove•Agawam,Massachoserts 01001 •413-789-9018•Fax 413.759-9076•u-syspectnun-analytical tom
.
Report Date: Final Report
16-Feb-06 10:58 0 Re-Issued Report
❑ Revised Report
SPECTRUM ANALYTICAL,INC.
Featuring
HANBALTECHNOLOGY
Laboratory Report
Environmental Compliance Services
588 Silver Street Project: Pro Corporation-PMC,Florence,M
Agawam,MA 01001 Project#: 01-201314.00.06
Attn: John Siedel
Laboratory ID Client Sample ID Matrix Date Sampled Date Re
SA40338-01 003A-1 Waste Water 03-Feb-06 08:19 03-Feb-C
SA40338-02 003A-2 Waste Water 03-Feb-06 10:06 03-Feb-C
SA40338-03 003A-3 Waste Water 03-Feb-06 12:05 03-Feb-(
SA40338-04 003A-4 Waste Water 03-Feb-06 14:14 03-Feb-(
SA40338-05 004A-I Waste Water 03-Feb-06 08:14 03-Feb-(
SA40338-06 004A-2 Waste Water 03-Feb-06 10:10 03-Feb-I
SA40338-07 004A-3 Waste Water 03-Feb-06 12:08 03-Feb-I
SA40338-08 004A-4 Waste Water 03-Feb-06 14:11 03-Feb-I
I attest that the information contained within the report has been reviewed for accuracy and checked against the quality t
requirements for each method. All applicable NELAC requirements have been met
Please note that this report contains 5 pages of analytical data plus Chain of Custody documen(s).
This report may not be reproduced,except in full.without written approval from Spectrum Analytical,Inc
Massachusetts Certification#M-MAI38/MA1110 . '*sized by:
Connecticut ft PH-0777 5 �1
Florida# A138 /E87936 su ncco,b . /
Maine#MAL38 er1 • 41C
New Hampshire#2538/2972 ,{9 -- �"�•
New York# 11393/11840 • 4` t anibal: --yeh,Ph.D
Rhode Island#98
USDA#S-51435 President/Laboratory D'.
Vermont VT-11393
Spectrum Analytical, Inc. is a NELAC accredited laboratory organization and meets NELAC testing standards. Use of
logo however does not insure that Spectrum is currently accredited for the specific method indicated. Please refer to o,
webpage at www.spectrum-analytical coin for a full listing of our current certifications.
ENVIRONMENTAL ANALYSES
II Almgren Drive•Agawam,Massachusetts 01001 •Operational Building&Sample Receiving
830 Silver Street•Agawam,Massachusetts 01001 •Administrative Offices,Volatile&Air Departments
1-800-789-91 I i •417-189.9018•Fax 417-789-4076
Sample Identification Client Project# Matrix Collection Date/Time Rec
003A-1 01-201314.00.06 Waste Water 03-Feb-06 08:19 03-F
SA40338-01
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed Ba
General Chemistry Parameters
7702-50.5 Total Residual Chlorine 0.880 mgll 0.200 10 Hach 8167 03-Feb-06 03-Feb-06 602
17:30
Sample Identification Client Protect# Matrix Collection Date/Time Re(
003A-2 01-201314.00.06 Waste Water 03-Feb-06 10:06 03-1
SA40338-02
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref Prepared Analyzed Bi
General Chemistry Parameters
778250.5 Total Residual Chlonne 0.255 mg4 0.100 5 Hach 8167 03-Feb-06 03-Feb-06 601
17:30
.xru:±r at 5. ..aum. msv-...v.tar
Sample Identification Client Project# Matrix Collection Date/Time Re
003A-3 01-201314.00.06 Waste Water 03-Feb-06 12:05 03-
SA40338-03
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed h
General Chemistry Parameters
n82-505 Total Residual Chlorine 0.840 mg4 0200 10 Hach 8167 03-Feb06 03-Feb-06 61
17:30
n_-Sample Wentification � Client Project Matrix Collection Date/Time Ri
003A-4 01-201314.00.06 Waste Water 03-Feb-06 14:14 03
SA40338-04
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed I
General Chemistry Parameters
702505 Total Residual Chlorine 1.48 mg4 0200 10 Hach 8167 03-Feb-06 03-Feb-06 6
17:30
.,P
Sample Identification Client Project# Matrix Collection Date/Time R
004A-1 01-201314.00.06 Waste Water 03-Feb-06 08:14 02
SA40338-05
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed
General Chemistry Parameters
78250.5 Total Residual Chlorine 1.22 mga 0.200 10 Hach 8167 03-Feb-06 03-Feb-06 1
17:30
Sample Identification Client Project 4 Matrix Collection Date/Time I
004A-2 01-201314.00.06 Waste Water 03-Feb-06 10:10 0
SA40338-06
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed
General Chemistry Parameters
7182.50-5 Total Residual Chlorite 127 mg4 0.200 10 Hach8167 03-Feb-06 03-Feb-06
17:30
This laboratory report is not valid without an authorized signature on the cover page.
*Reportable Detection Limit BRL=Below Reporting Limit
$ampleIdentifcation Client Project# Matrix Collection Date/Time Rec
004A-3 01-201314.00.06 Waste Water 03-Feb-06 12:08 03-F
SA40338-07
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed Ea
General Chemistry Parameters
77U-505 Total Residual Chlorine 1.58 mg/I 0.200 10 Hach 8167 03-Feb-06 03-Feb-06 602
17:30
Sample Identification Client Proiect# Matrix Collection Date/Time Rei
004A-4 01-201314.00.06 Waste Water 03-Feb-06 14:11 03-:
SA40338-08
CAS No. Analyte(s) Result Flag Units *RDL Dilution Method Ref. Prepared Analyzed Bi
General Chemistry Parameters
7782.50-5 Total Residual Chlorine 1.72 mg/ 0.200 10 Hach 8167 03-Feb-06 03-Feb-06 60:
17:30
This laboratory report is not valid without an authorized signature on the cover page.
Reportable Detection Limit BRL=Below Reporting Limit
Notes and Definitions
BRL Below Reporting Limit-Analyte NOT DETECTED at or above the reporting limit
dry Sample results reported on a dry weight basis
NR Not Reported
RPD Relative Percent Difference
A plus sign(+) in the Method Reference column indicates the method is not accredited by NELAC
Laboratory Control Sample(LCS): A known matrix spiked with compounds)representative of the target analytes,which
document laboratory performance
Matrix Duplicate: An intra-laboratory split sample which is used to document the precision of a method in a given samp
Matrix Spike: An aliquot of a sample spiked with a known concentration of target analyt(s). The spiking occurs prior t
preparation and analysis. A matrix spike is used to document the bias of a method in a given sample matrix
Method Blank: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sat
processing. The method blank should be carried through the complete sample preparation and analytical procedure The
blank is used to document contamination resulting from the analytical process
Method Detection Limit(MDL): The minimum concentration of a substance that can be measured and reported with99'
confidence that the analyte concentration is greater than zero and is determined from analysis of a sample in a given ma
containing the analyte.
Reportable Detection Limit(RDL): The lowest concentration that can be reliably achieved within specified limits of pn
accuracy during routine laboratory operating conditions For many analytes the RDL analyte concentration is selected a:
non-zero standard in the calibration curve.While the RDL is approximately 5 to 10 times the MDL,the RDL for each se
into account the sample volume'weight,extracVdigestate volume,cleanup procedures and,if applicable,dry weight con
Sample RDLs are highly matrix-dependent.
Sumo-ate: An organic compound which is similar to the target analytds)in chemical composition and behavior in the
process,but which is not normally found in environmental samples These compounds are spiked into all blanks,standh
Validated by:
Hanibal C.Tayeh,Ph.D.
Nicole Brown
This laboratory report is not valid without an authorized signature on the cover page.
*Reportable Detection Limit BRL=Below Reporting Limit
-- - - _ Special Handling: •
.,prT cs Standard TAT 7 to 10 business days
CHAIN OF CUSTODY RECORD El Rush TAT pate Needed:
All TA Fs subject to laboratory approval. '
s i. m Min.24-hour notification needed for rushes.
sve(rRUM ANALYTICAL.INC- Page I of I Samples disposed of atter 60 days unless•
nwsesie otherwise instructed
IANIBALTECNNOLOGY —
Report'io: Tn�N 'Sltc�-ZL Invoice To:
EGS Ac�tkwam Project No.:_ 0I-e1(h131 .00•
EGS Re) arm Site Name: PCb CacuS4Q Ca- 6-4
Location: PLoceticE State: MA
_ Sampler(s): I�M �t°nl
Project Mgr.: Sofa Stae�.eL P.O.No.: RQN:
l=Na25203 2=11CI 3=II2SO4 4=HNOe S=NaOH Analyses: QA Reporting Notes:6-Ascorbic Acid Containers: i (check if needed)
7=C:HIO}I B=Nat ISO, 9= �C-� I� ❑Provide MA DEP MCP CAM Report
DW=Drinking Water GW=Groundwater WW=Wastewater o ❑Provide Cr DPH RCP Report
0-011 SW=Surface Water S�Soil SL=Sludge A=Air m QA/QC Reporting Level
X1= X2= X3= - 9 V ❑Standard ❑No QC
E �' ❑Other
U N
G=Grab C=Composite -4 fina v yy > 6 V W �� State specific reporting standards'.
Lab Id: Sample Id: Date: Time: H� CL' h 0 0 0 EJ
a hr u a
Ma-0 Oo34-1 a./3/66 `6% 19 6 taw 9 I X
oo3R-A d/3/66 /6;06 6 taw 9 I X
03 Oo3A- 3 x/3/06 11 .05 6 wt:, 9 I X
o6 3A -N• a/3/66 r).. I14 6 taw 9 l 2K
r OS ocNA- I , e/3/66 'V IH 6 wW 7 I X
ooryA -1. d/3106 /6'. /0 e W`^t 4 _ I L`
m oo4A -3 d/3/66 Id'-O% 6 Leto 9 I X
004A N dl3/66 _ a'rll 6 Leto 9 I X
Relinquished by: Received by: Date: Time:
Fax results when available to(9 13_ 1559 -a-776 ` / .. - /0
fl F-tnnil to _ .-. /fie i — • .- ' -
FROM SPECTRUM ANALYTICAL (FRI) 4 14 2COE 1U:33/ST. 1C:29/NO. 55102:
Report Date: +q Final Report
14-Apr-06 10:11 0 Re-Issued Report
❑ Revised Report
SPECTRUM ANALYTICAL,INC
Feabpiag
HANIBAL TECHNOLOGY
Laboratory Report
Environmental Compliance Services
588 Silver Street Project: Pro Corporation-PMC,Florence,MA
Agawam,MA 01001 Project 01-201314.00,06
Attn:John Siedcl
Laboratory ID Client Sample ID Matrix Date Sampled Date Receives
SA43076-01 004A-1 Waste Water 07-Apr-0608:09 07-Apr-0615:1
SA43076-02 004A-2 Was°Water 07-Apr-06 10:02 07-Apr-06 15:1
SA43076-03 004A-3 Waste Water 07-Apr-06 12:04 07-Apr-06159
SA43076-04 004A-4 Waste Water 07-Apr-06 14:06 07-Apr-06151
SA43076-05 003A-1 Waste Water 07-Apr-06 U8:13 07-Apr-0615a
5A43076-06 003A-2 Waste Water 07-Apr-06 09:59 07-Apr-0615:
$A43076-07 003A-3 Waste Water 07-Apr-06 12:07 07-Apr-06 15:
SA43076-08 003A-4 Waste Water 07-Apr-06 14:10 07-Apr-06 15:
1 arrest that the information contained within the report has been reviewed for accuracy and checked against the quality control
requirements for each method. All applicable NELAC requirements have been met.
Please note that this report contains 4 pages of analytical data plus Chain of Custody document(s).
This report may not be reproduced,except in hill,without wrinen approval from Spectrum Analytical,Inc.
Massachusetts Certification M M-MA138/MA1110 • on d b
Connecticut PH-0777 •
Florida# 7 0lE87936
Maine q MA138
New Hampshire 4 2538/2972 ��
New York S 113931118401 I • eh,Ph,D.
USDA#5--55 144 75 5
U S President/La,.ratory Director
#
Vermont#VT-I 1393
Spectrum Analytical,Inc. is a NELAC accredited laboratory organization and meets NELAC testing standards We of the NI
logo however does not insure that Spectrum is currently accredited for the specific method indicated. Please refer to our"Qt
webpage at www.spectrum-analytIcal.com for a full listing of our current certifications.
FNVJRONMFNTAI AMP YcFf
I I Almgren Drive.Agawam,Massachusetts 01001 .Operational Building&Sample Receiving
830 Silver Street Agawam.Massachusetts 01001 Administrative Offices,Volatile A Air bepanmeuts pap,
1-8010-789-9115 1413789-9018'Fax 413-789-4076
FROM SPECTRUM ANALYTICAL (FRI) 4 14 2006 10:33/ST. 10:29/N0. 551023
Sample Identification Client Project# Matrix QQ.194°.fialLnaraila lcse.L.yj
004A-1 01-201314.00.06 Waste Water 07-Apr-06 08:09 07-Apr-06
SA43076-01
CAS No. Amine(+) Rash flag Units `RM. DiMdon Method Ref. Prepared Analyzed Batch A
General Chemistry Parameters 0100 5 Hazh 818] WIpnOS o]-Ap-0B 80092
T125a5 ToW RC6itlu91 Chbdne 0.955 10:00
Sample Identification Client Project# Matrix ,ollection DetefTimr Received
004A-2 01-201314.00.06 Waste Water 07-Apr-06 10:02 07-Apr-01
SA43076-02
GAS No. AroMyte(+)
Resat( Flag flits 'RDL DiWYvn Method$f Prepared Analyzed Batch r
General Chemistry Parameters
772€05 Total Residual Chlorins 0.900 mga 0.100 5 Hach B167 07.Apr06 07-Apr-06 604092
16:00
Sample Identification Client Proiect# Maki; Collection DalctTime Receive.
004A-3 01-201314.00.06 Waste Water 07-Apr 4/6 12:04 07-Apr4
SA43076-03
CAS No. Analyte(a) Result Flag Units 'RDL Dilution Method Ref. Prepared Analyzed Balch
General Chemistry?ammeters
7R2-50-5 Total Residual Chlorine 120 moll 0.500 25 Hach 8167 071800 06 07-Apr06 6040492
sample Identification Client Proiect# Matrix Collection Date/Time Recety!
004A-4 01-201314.00.06 Waste Water 07-Apr-0614:06 07-Apr-
SA43076-04
CAS No. Analyte(s) Result Flag Units VOL Dilution Method Ref. Prepared Analyzed Batch
General Chemistry Parameters p5p0 25 Hach 8187 07-Apr-06 0>Aq-08 6040492
7A2€P5 Total Residual CN011ne 1,48 aR4 18:00
Sample Identification Client ProiectII Matrix Collection DatefTime Receiv
003A-I 01-201314.00.06 Waste Water 07-Apr-0608:13 07-Apr
SA43076-05
CAS Na Analyte(e) Result Flag Units *RIM.• Dlludon Method Ref. Prepared Analyzed Batch
General Chemistry Parameters
7mbY+5 Total Residual Chldlne 1.10 mall 0.500 25 Hoch 9167 07.4r0 07-Apr-04 004049
1420
sSa_rnole identification Client Project# Matrix Collection Dateffime Recei,
003A-2 01.201314.00.06 Waste Water 07-Apr-06 09:59 07-Ap.
SA43076-06
CAS Na Analyte(s) Result Flag Units `RDL Dilution Method Ref. Prepared Analysed Bald
General Chemistry Pnramehn
742250-5 Total Residual Chbnne 0.785 mgu 0.100 5 Hach 8167 0718x-08 07-Apr-06 604041
TMs laboratory report is not valid without an authorized signature an the cover page.
•Reportable Detection limit DRL-Below Reporting Limit Pop
FROM SPECTRUM ANALYTICAL (FRI) 4 14 2606 10134/ST. 10:29/N0. 551023
Semple Identification Client Project II Matrix C lle do D t Tim Received
003A-3 01-201314.00.06 Waste Water 07-Apr-0612:07 07-Apr-06
SA43076-07
CAS Na. Anayte(s) Result Flag Units "ROL Dilation Method Ref Prepared Analysed Hatch .4
General Chemistry Parameters 0.500 Hach 8167 0]Ag06 OYapoOa 6040492
11rP565 Total Residual Ohbnce 120 16:00
Sample Identification Client Project# Matrix collection Dateffime Received
003A-4 01.201314.00.06 Waste Water 07-Apr-0614:10 07-Apr-01
SA43076-08
CAS No. Ana41e(s) Raab Flag Units 'RDL Dilation Method Ref. Prepared Analysed Hatch
General Chemtatry rerameten
rm.wu Total Residual Chlorine 1.52 mga 0.510 y Hach 8I67 07-Apr-06 07-Pq-06 6040402
1600
This laboratory report Is not valid without an authorized signature on the cover page.
•Reportable Detection Limit BILL=Below Reporting Limit Iag`
FROM SPECTRUM ANALYTICAL (FRI) 4 14 2006 10:34/ST. 10:29/NO. 551023
Notes and Definitions
BRL Below Reporting Limit-Analyte NOT DETECTED at or above the reporting limit
dry Sample results reported on a dry weight basis
Nit Not Reported
RPD Relative Percent Difference
A plus sign(+)in the Method Reference column indicates the method is not accredited by NELAC.
I
borato ry C ntrol Sam ple(I 5): A known matrix spiked with compound(s)representative of the target analytes.which is use
document laboratory performance.
Matrix Duplicate: An intra-laboratory split sample which is used to document the precision of o method in a given sample matt
Matrix Spike: An aliquot of a sample spiked with a known concentration of target analyte(s). The spiking occurs prior to saml
preparation and analysis. A matrix spike is used to document the bias of a method in a given sample matrix.
Method BIa0k: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sample
processing. The method blank should be carried through the complete sample preparation and analytical procedure. The meths
blank is used to document contamination resulting from the analytical process.
Method Detection Limit(MDLI: The minimum concentration of n substance that can be measured and reported with 99%
confidence that the analyte concentration is greater than zero and is determined from analysis of a sample in a given matrix typ
containing the analyze.
Bsaltable Detection Limit(RDLI: The lowest concentration that can be reliably achieved within specified limits of precision
accuracy during routine laboratory operating conditions.For many analytes the RDI.analyte concentration is selected as the lo
non-zero standard in the calibration curve.While the RDL is approximately 5 to 10 times the MDL,the RDL for each sample I
into account the sample volume/weight,extractfdigesmte volume,cleanup procedures and,if applicable,dry weight correction
Sample RDLs are highly matrix-dependent.
Surropate: An
but which its not normally found in environmentallssamples.I These compounds are spiked into all blanks,standards,al
process,
Validated by:
Hanibal C.Tayeh,Ph.D.
Nicole Brown
This laboratory report Is not valid without an authorized signature on the cover page. Pngi
•Reportable DalaMion Limit SRL=Below Reporting Limit
-, 1 CHAIN OF UUS I UL I x.[�L,U1 Ij : .All TATs subject 10 latocalory approval,CHAIN Min.24-hour notification needed for rushes.
Page�_of� • Samples disposed of after 60days unless
SPECTRUM AMAIxT,cAL6G otherwise instructed.
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